The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogen oxides / Cl oxides / ClOOCl / Hobe(2009)_4-6K_220-400nm(Ne matrix)

DATAFILE: ClOOCl_Hobe(2009)_4-6K_220-400nm(Ne matrix).txt
NAME: dichlorine dioxide, chlorine monoxide dimer, chlorine peroxide
FORMULA: ClOOCl
AUTHOR(YEAR): Hobe(2009)
T: 4-6K
λ: 220-400nm(Ne matrix)
BIBLIOGRAPHY: M. von Hobe, F. Stroh, H. Beckers, T. Benter, and H. Willner, "The UV/VIS absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl", Phys. Chem. Chem. Phys. 11, 1571-1580 (2009); DOI: 10.1039/B814373K
COMMENTS: ClOOCl isolated in Ne matrix

Absorbance measurements scaled to the absorption cross section at the maximum, 245 nm, as reported by

R.A. Cox and G.D. Hayman, "The stability and photochemistry of dimers of the ClO radical and implications for Antarctic ozone depletion", Nature 332, 796-800 (1988)

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